Tuesday 8 December 2015

Lecture 5 – Limiting Reactant

Limiting Reactant:

Limiting reactant is the reactant that limits the progress of the reaction by being lesser in quantity then required. The reaction therefore stops after the limiting reactant is used up.

Example:
Calculate the mass and volume of CO2 and H2O produced when 32g of CH4 is combusted with 32g of O2.

Equation:

Equation tells that:
16g of CH4 needs 64g of O2 to produce 44g of CO2 and 36g of H2O

Since, the quantities of both the reactants is given, first let us find the limiting reactant.

 32g of CH4 will need 128g of O2, but only 32g is available. Therefore, O2 is the limiting reactant and all calculations will be done according to this.

Therefore:




In this reaction only 8g of CH4 burns as after that all the O2 is used up and the reaction cannot go further.

Equation tells that:
16g of CH4 needs 64g of O2 to produce 44g of CO2 and 36g of H2O
According to the given situation:
8g of CH4 needs 32g of O2 to produce r g of CO2 and s g of H2O

i.                    Calculating the mass in grams of CO2 released after 8g of combustion of CH4 with 32g of O2:

22g of COis released after 8g of combustion of CH4 with 32g of O2

ii.                  Calculating the volume of CO2 released:


iii.                Calculating the mass in grams of H2O released after 8g of combustion of CH4 with 32g of O2:


18g of H2O  is released after 8g of combustion of CH4 with 32g of O2

iv.               Calculating the volume of H2O released:

Ideally, after the end of this reaction, Oxygen will be entirely used up while 24g of Methane will remain unreacted.