Tuesday 8 December 2015

Lecture 8 – Metallic Bonding

ACKNOWLEDGEMENT:

Figure
Source of Figure
Figure 20
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Figure 21
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Figure 22
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Figure 23
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Metallic Bonding:

Metal lattices are formed by metallic ions, closely packed together in a periodic arrangement, surrounded by a sea of electrons. These electrons are the valence electrons of each of the metal atom in the lattice.

Figure 20:
Table 11: Properties of Metals

Property
Reason
Metals are good conductors of electricity
The metallic ions are arranged in a sea of electrons valence electrons moving randomly. When a pd is applied, all these electron move towards the positive end of the applied pd and cause a current across the ends of the metal. These valence electrons make metals a good conductor of electricity.

Figure 21:




                    
Metals are good conductors of heat
The metallic ions are arranged in a sea of electrons valence electrons moving randomly. When an end of a metal is heated, the electrons in that region heat up, gain K.E, and collide with the surrounding ions and all the way towards the cold end of the metal. This heat transferred by heated electrons make metals a good conductor of heat.

Heat transfer is also happens through ions vibration but this is significantly slower than that by free electrons.

Figure 22:

Metals have high melting and boiling points
The arrangement is periodic and the interatomic forces of attraction between the ions are very strong. Therefore, metals have high melting and boiling points.

Note: The exception is mercury, it is metal with a melting point of -38.83°C, and exists as liquid at R.T.P.
Metals are malleable and ductile
Atoms in metals are regularly arranged, packed together with strong interatomic forces. These force are however, not rigid and when a large external force is applied, these layers of ions can slide over one another to make the metal malleable and ductile.

Malleability is the ability of a metal to be hammered into sheets.

Ductility is the ability of a metal to be drawn into wires.

Figure 23: