Thursday 10 December 2015

Lecture 8 – Rusting of Iron

ACKNOWLEDGEMENT:

Figure
Source of Figure
Figure 7
http://pixshark.com



Rusting of Iron:

Rusting of Iron is the process in which iron is oxidized to iron oxide in the presence of oxygen and water. 
Figure 6:
 
















Oxygen and moisture both are present in the air and thus rusting of iron is inevitable. Rusting is an environmental menace and poses a great threat to all iron structures and parts used in cities, machineries, plants, etc.

Prevention of rusting:

Iron can be protected from rusting by eliminating either one of the factors shown in Figure 6.

Figure 6:

 






Table 4 shows some of the techniques employed to prevent rusting of iron.

Table 4:

Technique
Rusting Factor Eliminated
Reasoning/ Explanation
Painting
O2 and H2O
A layer of paint prevents iron from rusting by eliminating off its contact with both atmospheric oxygen and moisture.
Greasing
O2 and H2O
A layer of oil and/or grease prevents iron from rusting by eliminating its contact with both atmospheric oxygen and moisture.
Plastic coating
O2 and H2O
Plastic coating iron material eliminates its contact with atmospheric oxygen and moisture to prevent rusting.
Galvanizing
O2 and H2O
Zinc is used to galvanize or coat the iron surface to prevent it from rusting by eliminating its exposure to atmospheric oxygen and moisture.

Sacrificial protection:

Sacrificial protection is another technique employed to prevent the corrosion of iron. In this technique, a more reactive metal; usually magnesium or zinc is attached to the iron structure using wires. Magnesium or zinc being more reactive than iron, oxidizes in preference to iron, thus preventing iron from rusting.



Magnesium or zinc blocks have to be periodically replaced to ensure the protection of iron.

Example:


Underwater pipes have magnesium attached to them to sacrificially protect the iron structure.

Figure 7: