Tuesday 5 January 2016

Lecture 1 – Acids: Introduction

ACKNOWLEDGEMENT:


Figure
Source of Figure
Figure 1
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Acids:

Acids are defined as solvents that produce Hydrogen, H+, ions as the only positive ions in their aqueous solutions, and whose pH is less than 7 on the pH scale.

pH Scale:

pH is defined as the – log of H+ ions concentration in an aqueous solution. The scale is a number line beginning from 0 and ending on 14. The pH of all acids ranges from 0 to 6, pH 7 is the pH of neutral solutions, while the pH of bases ranges from 8 to 14. The smaller the pH, the stronger the acid and the larger the pH the stronger the base.

Figure 1:


Calculating pH:

Acids:
pH = - log(H+ ions concentration in mol/dm3 or M)

Example 1: An aqueous solution of H2SO4 contains 1 x 10-3 M of H+ ions. Calculate its pH.
pH = - log(H+ ions concentration in mol/dm3 or M)
pH = - log (1 x 10-3)
pH = 3

Bases:
p(OH) = - log(OH- ions concentration in mol/dm3 or M)
pH = 14 – p(OH)

Example 2: An aqueous solution of NaOH contains 1 x 10-2 M of OH- ions. Calculate its pH.
p(OH) = - log(OH- ions concentration in mol/dm3 or M)
p(OH) = - log(1 x 10-2)
p(OH) = 2
pH = 14 – p(OH)
pH = 14 – 2
pH = 12

Table 1: Indicators and their colour change in acidic and basic medium

Indicator
Colour in Acids
Colour in Bases
pH at which colour changes
Litmus paper
Red
Blue
4.5 to 8.3
Methyl Orange
Red
Yellow
3.1 to 4.4
Screened Methyl Orange
Red
Green
3.2 to 4.5
Universal Indicator
Red
Voilent
7
Phenolphthalein
Colourless
Pink
8.3 to 10