Tuesday 8 December 2015

Lecture 4 – Covalent Compounds

ACKNOWLEDGEMENT:

Figure
Source of Figure
Figure 15
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Table 6a
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Table 6b
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Table 6c
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Table 6d
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Table 6e
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Table 6f
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Table 6g
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Table 6h
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Table 6i
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Table 6j
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Covalent Compounds:

Covalent compounds are formed between non-metals by the sharing of valence electrons. This type of bonding can be classified into:
i.                    Simple molecular bonding
ii.                  Macro molecular bonding

Simple Molecular Bonding:

Some compounds are formed by the reactions between non-metals to attain the noble gas electronic configuration by electron sharing. These bonds formed are not very strong and thus covalent compounds of this type have low melting and boiling points. Since, electrons are shared, and ions are absent, these compounds are non-conductors of electricity.

Consider the example of methane for understanding electron sharing in covalent compounds.

Figure 16:

The Carbon atom contain 4 valence electrons and requires 4 electrons to fill its valence shell. Hydrogen atom contains 1 electron in the K shell and require 1 more electron to fill its valence shell. By electron sharing, the compound of methane, CH4 is formed. In this, the valence shell of carbon is filled by the shared electrons of 4 atoms of hydrogen and the valence shell of each hydrogen is filled with 2 electrons. Thus, the valency of both the elements is satisfied. The absence of ions makes simple covalent compounds a non-conductor and the weak Vander Walls forces account for the low melting and boiling points.

Table 6: Some common simple covalent compounds and their dot and cross models

H2
Cl2

O2
       
HCl

N2

H2O

CH4

C2H6

CO2

NH3


Table 7: Properties of Simple Covalent Compounds

Property
Reason
Low melting and Boiling points
Weak Vander Walls forces of attraction between the shared electrons
Non-Conductors of electricity
Covalent compounds are non-conductors of electricity in any state as the electrons shared CANNOT move, and neither ions nor free electrons are present to carry the electric current