Thursday 10 December 2015

Lecture 4 – Presence of Carbon & Hydrogen in the Reactivity Series of Metals

Presence of Carbon and Hydrogen in the reactivity series:

Two non-metals Carbon and Hydrogen are present in the reactivity series. This is because Carbon and Hydrogen can, like more reactive metals, reduce metals below them in the series.

Example:

This reducing action of Carbon is utilized during the extraction of iron from its ore.

Example:
Hydrogen gas is passed over heated Copper oxide in a vacuumed tube. Hydrogen reduces Copper oxide to copper and forms water as a by-product.



Metal carbonates and their stability to heat:

All metal carbonates decompose to form metal oxides and carbon dioxide when heated. The amount of heat required for thermal decomposition suggest the stability of the carbonate. More reactive metals like Sodium and Potassium form more stable carbonates with high decomposition temperatures. As we move down the series, the decomposition temperatures decreases with calcium carbonate decomposing at around 850°C and magnesium carbonate at 350°C, while copper carbonate is decomposed to copper oxide and carbon dioxide in a lab using a Bunsen burner. Thus, stability of carbonates decreases down the series.

Table 4:

Metal
Symbol
Reactivity
Stability of the Carbonate to heat
Potassium
K

Sodium
Na
Calcium
Ca
Magnesium
Mg
Aluminium
Al
Zinc
Zn
Carbon
C
Iron
Fe
Lead
Pb
Hydrogen
H
Copper
Cu
Silver
Ag
Gold
Au
Platinum
Pt

Metals at the bottom of the series prefer to stay in atomic form.
Practical Example: Gold and Platinum are found uncombined in the earth's crust.