Tuesday 5 January 2016

Lecture 7 – Ammonia & the Harber’s Process

Nitrogen and Ammonia:

Ammonia is an industrially important gas and is widely used to manufacture fertilizers. It is industrially manufactures using Hydrogen and Nitrogen by the Harber’s Process.

Harber’s Process:

Nitrogen, obtained from the fractional distillation of liquid air and Hydrogen from Cracking of crude oil are made to react together in volumes of 1 : 3, respectively, at 450°C and 300atm in presence of Iron as a catalyst to yield Ammonia.


This is a reversible reaction; therefore the conditions are strictly maintained to ensure the maximum yield of Ammonia. It is an exothermic reaction; giving out heat and prefers low temperatures. The rate of the reaction however, decreases at low temperatures, therefore the temperature of 450°C is preferred to ensure a fast and maximum yield of ammonia,